path of file : /etc/sysconfig/network-scripts
modify route-eth0 or route-eth1 file on which ehternet interface you want to add route,
if file is not present create a file
# vi /etc/sysconfig/network-scripts/route-eth0
add following lines :
ADDRESS0=X.X.X.X
NETMASK0=X.X.X.X
GATEWAY0=X.X.X.X
example :
ADDRESS0=192.168.1.0
NETMASK0=255.255.255.0
GATEWAY0=192.168.2.1
IF YOU WANT MORE ROUTES TO BE ADDED, APPLY 1,2,3, ETC. INSTEAD OF 0